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Beilstein J. Org. Chem. 2008, 4, No. 47, doi:10.3762/bjoc.4.47
Graphical Abstract
Scheme 1: Synthesis of racemic aldehydes.
Scheme 2: Diastereoisomeric imidazolidines and oxazolidines from biaryl aldehydes.
Figure 1: X-ray crystal structure of 9a. X-ray data has been deposited with the Cambridge Crystallographic Da...
Figure 2: X-ray crystal structure of 10a. X-ray data has been deposited with the Cambridge Crystallographic D...
Scheme 3: Atropisomeric alcohols by hydrolysis and reduction.
Scheme 4: Mechanistic rationalisation of the dynamic resolution in the formation of 9.